The Next Generation episode that exemplifies key traits of their species.
First, they could show Q the episode "The Measure of a Man". This episode centers around a Starfleet court case considering the personhood and rights of the android Data. Legal precedents around the universe are considered, with Captain Picard passionately arguing for Data's individual freedoms. This episode demonstrates humanity's dedication to fairness and justice, no matter the complexity of the case at hand.
Secondly, the episode "Family" could be used to show Q the depth of human emotions and the importance of familial connections in their society. After the traumatic events with the Borg, Captain Picard returns to his family vineyard in France to spend time with his estranged elder brother. The two eventually manage to reconcile, showing Q humanity's capacity for forgiveness and healing.
Lastly, the episode "Yesterday's Enterprise" could be presented. In this one, the crew is thrown into an alternate timeline where they are at war with the Klingons. Despite the desperate situation, they eventually realize the truth and are willing to send the ship Enterprise-C back through time, knowing it will lead to their own death but will restore the peaceful timeline. This episode demonstrates humanity's bravery, self-sacrifice, and determination for peace.
By viewing these episodes, Q might gain insights about the complexities and worth of humanity, their emotional depth, as well as their relentless pursuit of justice, peace, and the importance of relationships.